Secondary Production of Gaseous Nitrated Phenols in Polluted Urban Environments

نویسندگان

چکیده

Nitrated phenols (NPs) are important atmospheric pollutants that affect air quality, radiation, and health. The recent development of the time-of-flight chemical ionization mass spectrometer (ToF-CIMS) allows quantitative online measurements NPs for a better understanding their sources environmental impacts. Herein, we deployed nitrate ions as reagent in ToF-CIMS quantified six classes gaseous Beijing. concentrations range 1 to 520 ng m–3. Nitrophenol (NPh) has greatest mean concentration. Dinitrophenol (DNP) shows haze-to-clean concentration ratio, which may be associated with aqueous production. high distinct diurnal profiles indicate strong secondary formation overweigh losses, driven by emissions precursors, oxidative capacity, NOx levels. budget analysis on basis our box-model calculations suggest minor role photolysis (<1 ppb h–1) producing OH radicals. therefore cannot explain underestimated production urban environments. Discrepancies between these results laboratory NP rates need further studies aimed at losses polluted

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ژورنال

عنوان ژورنال: Environmental Science & Technology

سال: 2021

ISSN: ['1520-5851', '0013-936X']

DOI: https://doi.org/10.1021/acs.est.0c07988